| 摘要 |
The present invention relates to new methods of making crystalline materials isostructural to ITQ-21, as well as to new crystalline materials obtainable by such methods, and their use in hydrocarbon conversion processes. In one of its aspects, the invention relates to a method of making a crystalline material iso-structural to ITQ-21, the method comprising: (a) providing a synthesis mixture comprising water, at least one source of germanium, at least one source of a tetravalent element X other than germanium, at least one structure directing agent R, optionally at least one source of trivalent element Y and optionally at least one source of fluoride, wherein the structure directing agent R is a compound of formula C1C2R1R2N+A-(I), in which C1 and C2 each independently represent a substituted or unsubstituted cyclohexyl or cyclopentyl group, R1 and R2 each independently represent a methyl group, an ethyl group or a propyl group, or R1 and R2 together with the nitrogen atom they are connected to form a ring containing 5 or 6 atoms, and A represents hydroxyl, fluorine, chlorine, bromine or iodine, (b) forming said crystalline material from the synthesis mixture; (c) recovering said crystalline material.
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