发明名称 CONVERSION OF A PRECATALYST TO A CATALYTICALLY ACTIVE SILVER-VANADIUM OXIDE BRONZE
摘要 A process is described for converting a precatalyst which comprises an inert support, an organic carbon source and a multimetal oxide comprising silver and vanadium to a gas phase oxidation catalyst which comprises the inert support and a catalytically active silver vanadium oxide bronze, by treating the precatalyst thermally at a temperature of at least 350° C. in a gas atmosphere which comprises less than 10% by volume of oxygen, wherein, before the thermal treatment, the amount of the carbon source in the precatalyst is adjusted to a value below a critical amount The carbon content is reduced by burning-off at a temperature of from 80 to 200° C. in an oxygenous atmosphere with decomposition of a portion of the carbon source. The catalysts obtained serve for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides.
申请公布号 US2009291845(A1) 申请公布日期 2009.11.26
申请号 US20060158858 申请日期 2006.12.20
申请人 BASF SE 发明人 NETO SAMUEL;HIBST HARTMUT;ROSOWSKI FRANK;STORCK SEBASTIAN;ZUEHLKE JUERGEN
分类号 B01J21/18 主分类号 B01J21/18
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