发明名称 Polyethylene stretch film
摘要 In one aspect is a film comprising: (a) within the range of from 50 to 99 wt % linear low density polyethylene based on the weight of the core composition; and (b) within the range of from 1 to 50 wt % propylene-α-olefin copolymer based on the weight of the core composition, wherein the propylene-α-olefin copolymer possesses: (i) a melting temperature (Tm) of less than 105° C., and (ii) a heat of fusion (Hf) of less than 75 J/g; wherein the film is a cast or blown film. The films have excellent strength and elasticity and are ideal for such applications as stretch wrap.
申请公布号 US9388306(B2) 申请公布日期 2016.07.12
申请号 US200812867871 申请日期 2008.03.04
申请人 ExxonMobil Chemical Patents Inc. 发明人 German Paul M.;Johnson Carlton B.;Williams Michael G.
分类号 B32B27/32;C08L23/06;C08L23/14;C08J5/18;C08L23/08;B32B27/08;B32B27/18 主分类号 B32B27/32
代理机构 代理人 Prasad Priya G.
主权项 1. A cast film comprising greater than 70 wt %, based on the weight of the cast film, of a core layer comprising a core composition comprising: (a) 50 to 99 wt % linear low density polyethylene based on the weight of the core composition; and (b) 1 to 50 wt % propylene-α-olefin copolymer based on the weight of the core composition, wherein the propylene-α-olefin copolymer comprises from 5 to 35 wt % of units derived from ethylene, less than or equal to 5 wt % of units derived from diene, with the balance being units derived from propylene, based on the total weight of the propylene-α-olefin copolymer, and wherein the propylene-α-olefin copolymer possesses: (i) a melting temperature (Tm) of less than 105° C.,(ii) a heat of fusion (Hf) of less than 75 J/g,(iii) a melt flow rate of 2 to 30 dg/min, and(iv) a density of 0.850 to 0.890 g/cm3, wherein the cast film is formed by using casting techniques, and has a MD gloss measured at a 45° angle of from about 89 to about 95 and a TD gloss measured at a 45° angle of from about 89 to about 95; and wherein a 20.3 μm thick cast film comprising the core composition possesses a strain hardening value at 2000 psi (13.78 MPa) of greater than 2% greater than the strain hardening value at 2000 psi of a 20.3 μm thick cast film comprising a core layer comprising a core composition consisting of only the linear low density polyethylene.
地址 Baytown TX US