PROCESSES AND SYSTEMS FOR PRODUCING PRODUCTS OF HYDROGENOLYSIS OF POLYHYDRIC ALCOHOLS
摘要
Hydrogenolysis systems are provided that can include a reactor housing an Ru-comprising hydrogenolysis catalyst and wherein the contents of the reactor is maintained at a neutral or acidic pH. Reactant reservoirs within the system can include a polyhydric alcohol compound and a base, wherein a weight ratio of the base to the compound is less than 0.05. Systems also include the product reservoir comprising a hydrogenolyzed polyhydric alcohol compound and salts of organic acids, and wherein the moles of base are substantially equivalent to the moles of salts or organic acids. Processes are provided that can include an Ru-comprising catalyst within a mixture having a neutral or acidic pH. A weight ratio of the base to the compound can be between 0.01 and 0.05 during exposing.
申请公布号
WO2009129256(A1)
申请公布日期
2009.10.22
申请号
WO2009US40551
申请日期
2009.04.14
申请人
BATTELLE MEMORIAL INSTITUTE;HOLLADAY, JOHNATHAN, E.;MUZATKO, DANIELLE, S.;WHITE, JAMES, F.;ZACHLER, ALAN, H.
发明人
HOLLADAY, JOHNATHAN, E.;MUZATKO, DANIELLE, S.;WHITE, JAMES, F.;ZACHLER, ALAN, H.