发明名称 FLUOROAMINE HAVING PERFLUOROALKYL GROUP, PROCESS FOR PRODUCING THE SAME, METHOD OF FLUORINATION THEREWITH, AND METHOD OF RECOVERING AMIDE HAVING PERFLUOROALKYL GROUP
摘要 <p>Provided are a fluorous-tag-introduced fluoroamine of a general formula (I), its production method, a method of fluorination of a substrate having functional group containing oxygen with the fluoroamine serving as a fluorinating agent, and a method of recovering a fluorous-tag-introduced amide after the fluorination. The fluoroamine and its production method, as well as the fluorination method with the fluoroamine and the method of recovery of a fluorous-tag-introduced amide are ecological and advantageous in industrial use, as the load for separating and collecting the product after the fluorination with the fluoroamine serving as a fluorinating agent is small. (In the formula, R 0 is an alkyl group or an aryl group having substituent(s) of Rf-(CH 2 ) m -; Rf is a perfluoroalkyl group; m is from 0 to 2; R 1 and R 2 each are an alkyl group or an aryl group.)</p>
申请公布号 EP2022776(A4) 申请公布日期 2009.10.21
申请号 EP20070766998 申请日期 2007.05.31
申请人 NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY;MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 HIDAKA, TOSHIO;YOSHIMURA, TAKAFUMI;HARA, SHOJI;FUKUHARA, TSUYOSHI
分类号 C07C211/15;C07C209/74 主分类号 C07C211/15
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