发明名称 |
Catalytic oligomerization of olefinic monomers |
摘要 |
A catalyst precursor composition comprising: a source of chromium, molybdenum or tungsten; a first ligand having the general formula (R1)(R2P—X—P(R3)(R4); and a second ligand having the general formula (R1′)(R2′)P—X′—P(R3′)(R4′). The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention. |
申请公布号 |
ZA200804073(B) |
申请公布日期 |
2009.09.30 |
申请号 |
ZA20080004073 |
申请日期 |
2008.05.13 |
申请人 |
SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. |
发明人 |
DE BOER, ERIC JOHANNES MARIA;VAN DER HEIJDEN, HARRY;ON, QUOC AN;SMIT, JOHAN PAUL;VAN ZON, ARIE |
分类号 |
B01J;C07C |
主分类号 |
B01J |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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