发明名称 |
CATALYST FOR THE POLYMERIZATION OF OLEFINS |
摘要 |
<p>The present invention relates to catalysts systems for the polymerization of ethylene and its mixtures with olefins CH2=CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, halogen, and optionally an electron donor compound in a donor/Ti molar ratio lower than 3, (B) an aluminum alkyl compound and (C) a silicon compound of formula XmR1 nSi(OR2)4-(m+n) in which X is bromine or fluoride or a halogen containing hydrocarbon group, R1 is a C1-C1O aliphatic or alicyclic group, R2 is C1-C1O alkyl group, m is an integer ranging from 1 to 3, n is 0 or 1 provided that the sum m+n is not higher than 3. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (copolymers having narrow Molecular Weight Distribution (MWD) and high activity.</p> |
申请公布号 |
WO2009112399(A1) |
申请公布日期 |
2009.09.17 |
申请号 |
WO2009EP52501 |
申请日期 |
2009.03.03 |
申请人 |
BASELL POLIOLEFINE ITALIA S.R.L.;FUSHIMI, MASAKI;SCHNEIDER, MARTIN;MORINI, GIAMPIERO |
发明人 |
FUSHIMI, MASAKI;SCHNEIDER, MARTIN;MORINI, GIAMPIERO |
分类号 |
C08F4/646;C08F4/654;C08F10/02 |
主分类号 |
C08F4/646 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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