发明名称 PROCESS FOR PRODUCING DICYANONORBORNANE AND ZEROVALENT NICKEL COMPLEX CATALYST
摘要 The present invention is to provide a process for producing dicyanonorbornane characterized by causing hydrogen cyanide to undergo addition reaction with cyanonorbornene (bicyclo[2.2.1]-5-heptene-2-carbonitrile) in the presence of a zerovalent nickel complex catalyst which is produced by using a phosphite represented by P(x)(y)(z) (wherein P is a phosphorus atom, and x, y and z are each OR, where R represents an aryl group having not more than 18 carbon atoms) as a ligand to reduce a nickel halide with at least one metal selected among zinc, cadmium, beryllium, aluminum, iron and cobalt, wherein the phosphite is one which has a phosphate content of 1.0 weight % or lower based on the whole phosphite.
申请公布号 US2009198082(A1) 申请公布日期 2009.08.06
申请号 US20070306889 申请日期 2007.06.22
申请人 MITSUI CHEMICALS , INC. 发明人 FUKATSU NORIHIKO;MORIJIRI HIROYUKI;SHIMAKAWA CHITOSHI;TOKUNAGA KOICHI;KOBAYASHI SEIICHI
分类号 C07C255/47;B01J31/22;C07C209/48;C07C253/10 主分类号 C07C255/47
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