发明名称 |
PROCESSES FOR PRODUCING CELLULOSE NANOFIBERS, CELLULOSE OXIDATION CATALYSTS AND METHODS FOR OXIDIZING CELLULOSE |
摘要 |
Disclosed is a process for producing a cellulose nanofiber by using a 4-hydroxy TEMPO derivative which is more inexpensive than TEMPO. Also disclosed is a process for producing a cellulose nanofiber homogeneously within a short period. Specifically disclosed is a process for producing a cellulose nanofiber, which is characterized by comprising the steps of: treating a cellulose raw material with an oxidizing agent in water in the presence of an N-oxyl compound represented by formula (1) or a mixture of the compounds and a cellulose oxidation catalyst selected from the group consisting of a bromide, an iodide and a mixture of the bromide and the iodide to produce an oxidized cellulose; and fibrillating the oxidized cellulose into a nanofiber. The process enable the production of a nanofiber from a wood cellulose with high efficiency. (In the formula (1), R1 and R2 independently represent a hydrogen or a linear or branched C1-C6 alkyl group; and (i) one of R4 and R5 represents -OR, -OCOR or -SO2R [wherein R represents a linear or branched carbon chain having 4 or less carbon atoms], and the other of R4 and R5 represents a hydrogen; and R3 and R6 independently represent a methyl group; or (ii) R4 represents a hydrogen; and R5, R3 and R6 together with a piperidine ring form an azaadamantane-type compound represented by formula (2).)
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申请公布号 |
CA2710550(A1) |
申请公布日期 |
2009.07.09 |
申请号 |
CA20082710550 |
申请日期 |
2008.12.25 |
申请人 |
NIPPON PAPER INDUSTRIES CO., LTD. |
发明人 |
MIYAWAKI, SHOICHI;KATSUKAWA, SHIHO;ABE, HIROSHI;IIJIMA, YUKO;ISOGAI, AKIRA |
分类号 |
D01F2/00;C08B15/02;D21H19/34 |
主分类号 |
D01F2/00 |
代理机构 |
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