发明名称 |
Method of preparing a poly(arylene ether) and a poly(arylene ether) prepared thereby |
摘要 |
The invention relates to a method of preparing a poly(arylene ether), comprising oxidatively coupling a monohydric phenol at a reaction temperature, T rxn , using an oxygen-containing gas in the presence of a solvent and a complex metal catalyst to produce a reaction mixture comprising a poly(arylene ether) resin; wherein the reaction mixture has a cloud point, T cloud and T rxn is greater than T cloud ; wherein the monohydric phenol comprises 2,6-dimethylphenol (DMP) and 2,3,6-trimethylphenol (TMP) in a weight ration DMP to TMP of 3:1 to 6:1; wherein the solvent comprises a C 6 -C 18 aromatic hydrocarbon; and wherein the complex metal catalyst comprises an alkylenediamine ligand having the formula
€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ (R b ) 2 N-R a -N(R b ) 2
wherein R a is a substituted of unsubstituted divalent residue wherein two or three aliphatic carbon atoms form the closest link between the two diamine nitrogen atoms; and each R b is independently hydrogen or C 1 -C 8 alkyl.
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申请公布号 |
EP2055731(A1) |
申请公布日期 |
2009.05.06 |
申请号 |
EP20090000367 |
申请日期 |
2002.10.28 |
申请人 |
SABIC INNOVATIVE PLASTICS IP B.V. |
发明人 |
BIRSAK, JOOP;INGELBRECHT, HUGO GERARD EDUARD;PARRILLO, DAVID;PARTHASARATHY, MUKUND;SINGH, PROBJOT |
分类号 |
C08G65/44 |
主分类号 |
C08G65/44 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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