发明名称 PROCESSES FOR PRODUCTION OF 2-BROMO-2,2-DIFLUOROETHANOL AND 2-(ALKYLCARBONYLOXY)-1,1-DIFLUOROETHANESULFONIC ACID SALT
摘要 <p>Disclosed is a process for producing 2-bromo-2,2- difluoroethanol, which comprises reducing a bromodifluoroacetic acid derivative represented by the formula [1] by using an ate hydride complex as a reducing agent. 2-Bromo-2,2-difluoroethanol thus produced can be used as a starting material to carry out the esterification step, the sulfination step and the oxidation step in this order, thereby producing a 2-alkylcarbonyloxy-1,1-difluoroethanesulfonic acid salt, wherein A represents a substituted or unsubstituted linear, branched or cyclic alkoxy group having 1 to 20 carbon atoms, a substituted of unsubstituted aryloxy group having 6 to 15 carbon atoms, a heteroaryloxy group having 4 to 15 carbon atoms, or a halogen atom.</p>
申请公布号 WO2009037980(A1) 申请公布日期 2009.03.26
申请号 WO2008JP66041 申请日期 2008.09.05
申请人 CENTRAL GLASS COMPANY, LIMITED;JODRY, JONATHAN JOACHIM;NAGAMORI, MASASHI;HAGIWARA, YUJI;FUJIWARA, MASAKI;NARIZUKA, SATORU 发明人 JODRY, JONATHAN JOACHIM;NAGAMORI, MASASHI;HAGIWARA, YUJI;FUJIWARA, MASAKI;NARIZUKA, SATORU
分类号 C07C29/147;C07C31/34;C07C303/00;C07C309/08;C07C309/10;C07C309/12;C07C381/12 主分类号 C07C29/147
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