| 摘要 |
FIELD: chemistry. ^ SUBSTANCE: invention concerns sphere of metal-organic synthesis, particularly method of obtaining new 1-chloro-3,4-dialkyl-2,5-bis[3-(1-alkinyl)phenyl]-1H-aluminol compounds. Method involves reaction of 1,4-di(1-alkinyl)benzenes with AlCl3 and metal Mg in the presence of zirconocene dichloride catalyst in argon atmosphere at room temperature in tetrahydrofuran for 14-18 hours. Obtained compounds can be applied as catalytic system components in polymerisation and oligomerisation processes for olefins and diene hydrocarbons, in industrial-scale fineorganic and metal-organic synthesis, and in bioactive medicine synthesis. ^ EFFECT: efficient method of obtaining new 1-chloro-3,4-dialkyl-2,5-bis[3-(1-alkinyl)phenyl]-1H-aluminol compounds. ^ 1 cl, 1 ex, 1 tbl |
