METHOD OF OBTAINING POLYHYDRO[60]FULLERENES

摘要

FIELD: chemistry. ^ SUBSTANCE: invention concerns method of obtaining polyhydro[60]fullerenes of formula (1): , involving fullerene C60 interaction with ethylaluminium dichloride (EtAlCl2) in the presence of magnesium powder and titanocene dichloride catalyst (Cp2TiCl2) at molar ratio of C60:EtAlCl2:Mg:Cp2TiCl2=1:(55-65):(55-65):(0.15-0.25), preferably 1:60:60:0.20, in argon atmosphere in the absence of light at room temperature of (20-21°C) and atmospheric pressure in toluene and tetrahydrofuran medium for 1-3 hours, with further hydrolysis of reaction mass. The method allows obtaining 72-86% output of polyhydro[60]fullerene after reaction mass hydrolysis. ^ EFFECT: improved method. ^ 1 tbl, 7 ex