发明名称 METHOD FOR PRODUCING 2,5-FURAN DICARBOXYLIC ACID
摘要 PROBLEM TO BE SOLVED: To provide a method for producing 2,5-furan dicarboxylic acid, by which the 2,5-furan dicarboxylic acid can efficiently be produced in mild reaction conditions at a low cost, without needing an expensive catalyst and solvent. SOLUTION: This method for producing the 2,5-furan dicarboxylic acid (hereinafter referred to as FDCA), comprising subjecting 2-carboxy-5-formyl fuarn (hereinafter referred to as CFF) to a Cannizzaro reaction in an aqueous solution under an alkaline environment, is characterized by adding a catalyst and an oxidizing agent to the aqueous solution subjected to the Cannizzaro reaction to oxidize 5-hydroxymethyl-2-furan carboxylic acid (hereinafter referred to as HMFA) by-produced in the reaction to recover CFF, which is supplied to the Cannizzaro reaction. COPYRIGHT: (C)2009,JPO&INPIT
申请公布号 JP2009023916(A) 申请公布日期 2009.02.05
申请号 JP20070185504 申请日期 2007.07.17
申请人 CANON INC 发明人 KAKINUMA HIROKAZU;MATSUHISA HIROHIDE;MIURA TOSHINARI;KONO TAKENOBU
分类号 C07D307/68;C07B61/00 主分类号 C07D307/68
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