发明名称 VERFAHREN ZUR ISOMERISIERUNG VON ALLYLALKOHOLEN
摘要 The present invention relates to a process for isomerizing reactant allyl alcohols of the formula (I) to product allyl alcohols of the general formula (II) where R1 to R5 are each hydrogen or a mono- or polyunsaturated or saturated C<SUB>1</SUB>-C<SUB>12</SUB>-alkyl radical, which can be substituted or unsubstituted, in both directions of the equilibrium, which comprises isomerizing in the presence of a dioxotungsten(VI) complex of the general formula (III), where L<SUB>1</SUB>, L<SUB>2 </SUB>are each independently a ligand selected from the group consisting of the aminoalcohols, the aminophenols and mixtures thereof, m, n are each 1 or 2, new dioxotungsten(VI) complexes, and also their use.
申请公布号 DE50213036(D1) 申请公布日期 2009.01.02
申请号 DE2002513036 申请日期 2002.12.04
申请人 BASF SE 发明人 HAESE, FRANK;EBEL, KLAUS
分类号 B01J23/30;C07D215/26;B01J31/22;B01J31/34;C07B61/00;C07C29/56;C07C33/02;C07C33/03;C07F11/00 主分类号 B01J23/30
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