FLUORINATED COMPOSITIONS AND SURFACE TREATMENTS MADE THEREFROM

摘要

A composition comprising at least one first divalent unit represented by formula (A) or formula (B); and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of -P(O)(OY)2 and -O-P(O)(OY)2. Rf is a perfluoropolyether group. Q is selected from the group consisting of a bond, -C(O)-N(R1)-, and -C(O)-O-. R", R'", R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. X is selected from the group consisting of alkylene, arylalkylene, and alkylarylene, wherein alkylene, arylalkylene, and alkylarylene are each optionally interrupted by at least one ether linkage. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.