| 摘要 |
1438107 Gas analysis BRITISH GAS CORP 15 Aug 1973 [21 Sept 1972] 43823/72 Heading G1N Apparatus for measuring low concentrations of nitrogen oxides and carbon monoxide in a gas separates the gas into two streams, removes interfering gases from the first stream and reacts the carbon monoxide therein with iodine pentoxide yielding iodine, passes the iodine containing stream and the second stream through associated cells each comprising a platinum cathode over which the gases flow, in contact with a neutral buffered halide electrolyte containing an active carbon or silver anode and measures the rate of gas flow through each cell and the resulting electric currents. Bell construction. (Fig. 2) The cell has a platinum mesh cathode 105 wrapped in sheets of glass fibre paper 106. The anode comprises an active carbon paste 103 surrounding a platinum mesh 104 and is immersed in electrolyte 111 which fills the cell up to level 110. The electrolyte is phosphate buffered KC 1 in water/glycer or digol and the electrodes are seperated by sintered glass disc 107. The gas enters by tube 108 and leaves by tube 109. Flow paths (Fig. 1A) The measurement for CO is carried out in the first (left hand) path. The incoming gas is passed through acidfied CrO 3 (1) and charcoal (2) which removes nitric oxide, nitrogen dioxide, hydrogen sulphide, sulphur dioxide, ozone, ethylene and acetylene. It is dried by silica gel or anhydrous calcium sulphate at (3) and passed either through 5 in which the CO is oxidized to CO 2 for zeroing the measurements or direct to heated section vessel 6 where the CO reacts with I 2 O 5 at 150‹C. The resulting iodine is measured by the current in cell 7. The gas flow is measured at 8' and controlled by valves; pump 9 providing the necessary pressure head. The gas in the second path is optionally scrubbed at 10 with silver peroxide to remove sulphur dioxide, hydrogen sulphide, ozone and mercaptors. It is then passed either through 12 which contains active carbon or soda lime to absorb NO 2 for zeroing or direct and then either direct to the measuring cell or through oxidizer 14 which oxidizes NO present to NO 2 . The flow is measured as before by meters 8'. In an alternative embodiment for measuring both NO and NO 2 means are provided for both absorbing NO 2 e.g. activated carbon or triethanolamine or to oxidize NO to NO 2 (e.g. chromium trioxide or dichromate) (preferably preceded by FeSO 4 to remove ozone) so that NO and total NO 2 after oxidization of NO can be measured. |
