发明名称 SEMICONDUCTOR CERAMIC CAPACITOR OF GRAIN-BOUNDARY INSULATION TYPE
摘要 PURPOSE:To obtain this capacitor by a method wherein a sintering-promoting additive, a semiconductor-promoting additive and a grain-boundary depletion- layer forming agent, in respectively prescribed quantities, are added to a perovskite-type oxide composed mainly of SrTiO3, this mixture is sintered and a diffusion treatment is executed in an oxidizing atmosphere. CONSTITUTION:The following are added to and mixed with a perovskite-type oxide composed mainly of strontium titanate (SrTiO3): 0.1 to 5.0wt.% of a sintering-promoting additive; 0.05 to 2.0wt.% of a semiconductor-promoting additive Nb2O5; and 0.1 to 5.0wt.% of a grain-boundary depletion-layer forming agent composed of Sr1-x-yBaxCay(Co1/3Ta2/3)O3 (where x<=0.3, y<=0.3 and 0<=x+y<=0.6). This mixture is pressurized and molded. Then, the mixture is baked at 1250 to 1500 deg.C in a reducing atmosphere which contains hydrogen. The surface of its baked substance is coated with a grain-boundary diffusing substance which contains bismuth oxide (Bi2O3). A heat treatment is executed at 850 to 1200 deg.C in an oxidizing atmosphere. Electrodes are formed. Thereby, a large element whose characteristic is good can be obtained.
申请公布号 JPH04112516(A) 申请公布日期 1992.04.14
申请号 JP19900231743 申请日期 1990.08.31
申请人 MATSUSHITA ELECTRIC IND CO LTD 发明人 IGA ATSUSHI
分类号 C04B35/46;C23C8/40;H01B3/12;H01G4/12 主分类号 C04B35/46
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