摘要 |
The present invention relates to alkyl ether sulfate salts of the general formula I <?in-line-formulae description="In-line Formulae" end="lead"?>RO-(CH<SUB>2</SUB>CH<SUB>2</SUB>O)<SUB>x</SUB>-(CH<SUB>2</SUB>-CHR<SUP>1</SUP>O)<SUB>y</SUB>-(CH<SUB>2</SUB>CH<SUB>2</SUB>O)<SUB>z</SUB>SO<SUB>3</SUB><SUP>-</SUP>M<SUP>+</SUP>, (I)<?in-line-formulae description="In-line Formulae" end="tail"?> where R is an unbranched or branched C<SUB>8</SUB>-C<SUB>18</SUB>-alkyl radical or mixtures of different unbranched or branched C<SUB>8</SUB>-C<SUB>18</SUB>-alkyl radicals, R<SUP>1 </SUP>is an aliphatic radical selected from the group consisting of methyl and ethyl, M<SUP>+</SUP> is a cation, selected from the group consisting of alkali metals, NH<SUB>4</SUB><SUP>+</SUP> and HNR<SUP>2</SUP><SUB>3</SUB><SUP>+</SUP>, where R<SUP>2 </SUP>is selected from the group consisting of unbranched or branched alkyl radicals, CH<SUB>2</SUB>CH<SUB>2</SUB>OH and CH<SUB>2</SUB>CH(OH)CH<SUB>3</SUB>, x has a mean value of 0-3, y has a mean value of 1-10, z has a mean value of 0-30, and the quotient <maths id="MATH-US-00001" num="00001"> <MATH OVERFLOW="SCROLL"> <MROW> <MI>A</MI> <MO>=</MO> <MROW> <MROW> <MFRAC> <MROW> <MI>c</MI> <MO></MO> <MSTYLE> <mspace width="0.3em" height="0.3ex"/> </MSTYLE> <MO></MO> <MI>m</MI> <MO></MO> <MSTYLE> <mspace width="0.3em" height="0.3ex"/> </MSTYLE> <MO></MO> <MROW> <MI>c</MI> <MO></MO> <MROW> <MO>(</MO> <MROW> <MI>RO</MI> <MO>-</MO> <MROW> <MSUB> <MROW> <MO>(</MO> <MROW> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO></MO> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO></MO> <MI>O</MI> </MROW> <MO>)</MO> </MROW> <MI>z</MI> </MSUB> <MO></MO> <MSUBSUP> <MI>SO</MI> <MN>3</MN> <MO>-</MO> </MSUBSUP> <MO></MO> <MSUP> <MI>M</MI> <MO>+</MO> </MSUP> </MROW> </MROW> <MO>)</MO> </MROW> </MROW> </MROW> <MTABLE> <MTR> <MTD> <MROW> <MI>c</MI> <MO></MO> <MSTYLE> <mspace width="0.3em" height="0.3ex"/> </MSTYLE> <MO></MO> <MI>m</MI> <MO></MO> <MSTYLE> <mspace width="0.3em" height="0.3ex"/> </MSTYLE> <MO></MO> <MROW> <MI>c</MI> <MO>(</MO> <MROW> <MI>RO</MI> <MO>-</MO> <MSUB> <MROW> <MO>(</MO> <MROW> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO></MO> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO></MO> <MI>O</MI> </MROW> <MO>)</MO> </MROW> <MI>x</MI> </MSUB> <MO>-</MO> </MROW> </MROW> </MROW> </MTD> </MTR> <MTR> <MTD> <MROW> <MROW> <MSUB> <MROW> <MO>(</MO> <MROW> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO>-</MO> <MROW> <MSUP> <MI>CHR</MI> <MN>1</MN> </MSUP> <MO></MO> <MI>O</MI> </MROW> </MROW> <MO>)</MO> </MROW> <MI>y</MI> </MSUB> <MO>-</MO> <MROW> <MSUB> <MROW> <MO>(</MO> <MROW> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO></MO> <MSUB> <MI>CH</MI> <MN>2</MN> </MSUB> <MO></MO> <MI>O</MI> </MROW> <MO>)</MO> </MROW> <MI>z</MI> </MSUB> <MO></MO> <MSUBSUP> <MI>SO</MI> <MN>3</MN> <MO>-</MO> </MSUBSUP> <MO></MO> <MSUP> <MI>M</MI> <MO>+</MO> </MSUP> </MROW> </MROW> <MO>)</MO> </MROW> </MTD> </MTR> </MTABLE> </MFRAC> <MO></MO> <MSTYLE> <mspace width="0.8em" height="0.8ex"/> </MSTYLE> <MO></MO> <MI>is</MI> </MROW> <MO>></MO> <MN>1</MN> </MROW> </MROW> </MATH> </MATHS> and to their use as anion surfactant component in laundry detergents and cleaning compositions, in chemical engineering applications or in cosmetics formulations.
|