Physical vapor deposition methods for forming hydrogen-stuffed trench liners for copper-based metallization

摘要

Copper-based metallization is formed in a trench on an integrated circuit substrate by forming a liner of refractory metal in the trench using physical vapor deposition, forming a copper plating seed layer on the liner using physical vapor deposition and then plating copper on the copper plating seed layer. Prior to plating copper on the copper plating seed layer, the liner and/or copper plating seed layer is stuffed with hydrogen, for example by exposing the liner and/or copper plating seed layer to a hydrogen-containing plasma during and/or after formation of the liner and/or copper plating seed layer. Related structures also are disclosed.