发明名称 METHOD FOR PRODUCTION OF POLYCYCLIC (METH)ACRYLATE INCLUDING CYANO GROUPS
摘要 PROBLEM TO BE SOLVED: To provide a method for inexpensively and industrially practicably producing a cyano group-containing polycyclic (meth)acrylate important as a material monomer for industrial use such as optical materials, and to provide the cyano group-containing polycyclic (meth)acrylate less in the content of (meth)acrylic anhydride. SOLUTION: The cyano group-containing polycyclic (meth)acrylate represented by general formula (2) is produced by adding (meth)acrylic acid to a cyano group-containing polycyclic olefin represented by general formula (1) in the presence of an acid catalyst. In this case, addition reaction is performed while the molar ratio of the content of (meth)acrylic acid to that of the cyano group having the polycyclic olefin in a reaction system is kept to be≥3.5. In formulas (1) and (2), R<SB>1</SB>is H or methyl; R<SB>2</SB>and R<SB>3</SB>are each H or cyano, provided that at least one of R<SB>2</SB>and R<SB>3</SB>is cyano; and n is an integer of 0 to 2. COPYRIGHT: (C)2006,JPO&NCIPI
申请公布号 JP2006117549(A) 申请公布日期 2006.05.11
申请号 JP20040304450 申请日期 2004.10.19
申请人 MITSUBISHI CHEMICALS CORP 发明人 KAWARAGI YUJI;NAITO TAKETOSHI;OKAGO YUJI;ICHIKAWA SHUJI
分类号 C07C253/30;C07B61/00;C07C255/47 主分类号 C07C253/30
代理机构 代理人
主权项
地址