摘要 |
The present invention provides a method of producing a solid oxide fuel cell, comprising the steps of: forming an anode support layer; applying an anode layer on the anode support layer; applying an electrolyte layer on the anode layer; and sintering the obtained structure; wherein the anode support layer and/or the anode layer comprises a composition comprising doped zirconia, doped ceria and/or a metal oxide with an oxygen ion or proton conductivity, NiO and at least one oxide selected from the group consisting of AI<SUB>2</SUB>O<SUB>3</SUB>, TiO<SUB>2</SUB>, Cr<SUB>2</SUB>O<SUB>3</SUB>, Sc<SUB>2</SUB>O<SUB>3</SUB>, VO<SUB>x</SUB>, TaO<SUB>x</SUB>, MnO<SUB>x</SUB>, NbO<SUB>x</SUB>, CaO, Bi<SUB>2</SUB>O<SUB>3</SUB>, LnO<SUB>x</SUB>, MgCr<SUB>2</SUB>O<SUB>4</SUB>, MgTiO<SUB>3</SUB>, CaAI<SUB>2</SUB>O<SUB>4</SUB>, LaAIO<SUB>3</SUB>, YbCrO<SUB>3</SUB>, ErCrO<SUB>4</SUB>, NiTiO<SUB>3</SUB>, NiCr<SUB>2</SUB>O<SUB>4</SUB>, and mixtures thereof. According to the invention, a combination of nickel coarsening prevention due to specific Ni-particle growth inhibitors, and, at the same time, a strengthening of the ceramic structure of the anode support layer and/or the anode layer is achieved.
|