| 摘要 |
The free radical initiated addition polymerisation of ethylenically unsaturated, particularly acrylic monomers in which the dispersed phase is stabilised by a surfactant including at least one anionic surfactan t compound of the formula (1): R1 -(OA)n- X where R1 is C16 to C22 hydrocarbyl including at least two double bonds; OA is oxyalkylene group; n is from 2 to 60; and X includes at least one acidic H atom, and is particularly a phosphate ester group, or a salt thereof, is described. The use of the surfactants of the formula (I) enable efficient emulsification and thus polymerisation at temperatures above those at which non-ionic unsaturated surfactants are effective. The polymer latex products give polymer films having good water resistance properties.
|
