SUBSTITUTED IRON PHTHALOCYANINES AND METHOD OF OBTAINING CHLOR-DERIVATIVES OF AROMATIC HYDROCARBONS

摘要

FIELD: chemistry. ^ SUBSTANCE: as catalyst substituted iron phthalocyanines of general formula , ^ where R=[CH2N+(CH3)2CH2CH2OH]Cl-, L=(CH3)2NCH2CH2OH (I); ^ R=[CH2N+(CH3)2CH2CH2N(CH3)2]Cl-, L=(CH3)2NCH2CH2N(CH3)2 (III); ^ are used. Oxychlorination is carried out with mixture of H2O2 and HCl in water-alcohol medium in presence of suggested catalyst. ^ EFFECT: simplification of technology of obtaining chlor-derivatives of aromatic hydrocarbons with good yield and quality of product. ^ 2 cl, 19 ex