An organic field-effect transistor comprising: a source region; a drain region; one or more organic semiconductor layers disposed between the source and drain regions; a gate region; and a dielectric region disposed between the organic semiconductor layer(s) and the gate region; wherein the composition of the organic semiconductor layer(s) is such as to transport both electrons and holes, with the mobility of the holes being substantially equal to the mobility of the electrons such that the transistor substantially exhibits ambipolarity in its transfer characteristics. The organic field-effect transistor is preferably a light-sensing organic field-effect transistor. Numerous modifications to the composition and structure of organic field-effect transistors are also disclosed, as are examples of electro-optical switches, electro-optical logic circuits and image sensing arrays.