| 摘要 |
Catalytic processes are taught for oxidative chemical conversion of gaseous reactants comprising methane, natural gas or other gaseous compounds combined with air or oxygen to products and catalytic methanation of resulting oxidized products comprising alcohols, aldehydes, ketones, glycol ethers and aldols to condensable hydrocarbons using methane, natural gas or other gaseous hydrocarbons. Gaseous reactants including methane, ethane, propane, oxides of carbon, unsaturated compounds and other organic compounds with conversion to condensable hydrocarbons by this catalytic process. The catalysts are based on di-metal, tri-metal and/or poly-metal backbone or molecular string type compounds of transition metals, comprising titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, molybdenum, ruthenium, rhodium, palladium, silver, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold and combinations thereof in conjunction with a non-fluoride magnesium halide.
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