| 摘要 |
<p>A method for preparing a silver nanoparticle-dispersed resin is provided to avoid the use of a separate physical dispersion device or dispersing agent, thereby simplifying the overall process and realizing excellent cost efficiency. A method for preparing a silver nanoparticle-dispersed resin comprises the steps of: dissolving a silver complex compound into a vinyl monomer, wherein the silver complex is obtained by reacting a silver compound represented by the following formula 1 with at least one compound selected from ammonium carbamate compounds, ammonium carbonate compounds and ammonium bicarbonate compounds represented by the following formulae 2-4; and carrying out radical polymerization of the vinyl monomer. In the formulae, X is a substituent selected from O, S, halogen, cyano, cyanate, carbonate, nitrate, nitrite, sulfate, phosphate, thiocyanate, chlorate, perchlorate, tetrafluoroborate, acetylacetonate, carbonylate and derivatives thereof; n is an integer of 1-4; and each of R1-R6 is selected from H, OH, a C1-C30 alkoxy, C3-C20 aryloxy, C1-C30 aliphatic or C3-C20 alicyclic alkyl or C3-C20 aryl or C4-C30 aralkyl, substituted C1-C30 alkyl, substituted C4-C30 aralkyl, C3-C20 heterocyclic compound containing a heteroatom selected from N, S and O, and polymers and derivatives thereof, wherein when each of R1-R6 is a substituted or non-substituted alkyl or aralkyl, it optionally further comprises a heteroatom selected from N, S and O and an unsaturated bond in the carbon chain, and R1 and R2, or R4 and R5 optionally form a ring by being linked to each other via an alkylene group optionally containing a heteroatom.</p> |
