发明名称 MANUFACTURING METHOD OF SECONDARY ALCOHOL OR DIKETONE COMPOUND USING KETONE COMPOUND
摘要 PROBLEM TO BE SOLVED: To provide a novel reduction reaction for synthesizing a secondary alcohol or a diketone with a ketone as a raw material neither using an expensive and noxious metal hydride or a metal salt nor restricted under an inactive gas atmosphere as is in the current method. SOLUTION: In this manufacturing method, a secondary alcohol or a diketone compound is synthesized by reducing a ketone compound in a solvent using as a reducing agent a 12CaO-7Al<SB>2</SB>O<SB>3</SB>electride containing not less than 10<SP>19</SP>cm<SP>-3</SP>but not more than 2.3×10<SP>21</SP>cm<SP>-3</SP>electrons in a cage. COPYRIGHT: (C)2008,JPO&INPIT
申请公布号 JP2008214302(A) 申请公布日期 2008.09.18
申请号 JP20070056820 申请日期 2007.03.07
申请人 JAPAN SCIENCE & TECHNOLOGY AGENCY 发明人 HOSONO HIDEO;BUCHAMMAGARI HARITHA;TODA YOSHITAKE;HIRANO MASAHIRO;KOSAKATA KOTARO;TAKEUCHI DAISUKE
分类号 C07C29/136;C07C33/24;C07C41/18;C07C43/20;C07C45/68;C07C49/675;C07C49/83;C07C253/30;C07C255/53 主分类号 C07C29/136
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