Two-stage chemi-mechanical pretreatment for lignocellulosic biomass

摘要

A process for pretreating lignocellulosic biomass that increases monomeric sugar yields in subsequent enzymatic hydrolysis and reduces specific energy consumption during production of the hydrolysable material. The pretreatment includes a chemical treatment followed by a mechanical size reduction such as a disc refining step, and includes a second chemical treatment, harsher than the first, which may precede or follow the size reduction.

主权项

1. A method for treating wood chips, the method comprising the steps of:
(i) exposing a first mixture comprising the wood chips and an aqueous sulfuric acid solution, between about 1.0 and about 1.5% (w/w), at a temperature of between about 150° C. and about 180° C. for a period of time between about 15 and about 30 minutes, wherein the mixture has a consistency of between about 10 and about 25%, to at least partially hydrolyze hemicellulose of the wood chips; (ii) removing xylose and mannose produced in step (i) from the mixture; (iii) exposing a second mixture comprising the wood chips produced in step (i) and an aqueous sulfuric acid solution, between about 3.0 and about 10% (w/w), at a temperature of between about 180° C. and about 220° C., wherein the second mixture has a consistency of between about 10 and about 25%, to at least partially hydrolyze hemicellulose of the wood chips; and (iv) physically reducing the wood chips produced in step (iii) by disc refining to produce cellulosic fibers which will undergo hydrolysis to produce glucose at a yield of at least 90% in presence of a cellulase dosage of 15 FPU/g glucan, and wherein net specific energy consumed in step (iv) is reduced by between 70 and 95 percent when compared to disc refining of the same amount of wood chips not subjected to acid treatment under the same disc refining conditions of step (iv).