发明名称 |
INDUSTRIAL PROCESS FOR PRODUCTION OF HIGH-PURITY DIPHENYL CARBONATE |
摘要 |
It is an object of the present invention to provide a specific process that enables a high-purity diphenyl carbonate that can be used as a raw material of a high-quality and high-performance polycarbonate to be produced stably for a prolonged period of time on an industrial scale of not less than 1 ton / hr from a reaction mixture containing a catalyst and reaction by-products that has been obtained through transesterification reaction and the like using a dialkyl carbonate and a phenol as a starting material. Although there have been various proposals regarding processes for the production of reaction mixtures containing aromatic carbonates by means of a reactive distillation method, these have all been on a small scale and short operating time laboratory level, and there have been no disclosures on a specific process or apparatus enabling mass production on an industrial scale from such a reaction mixture to a high-purity diphenyl carbonate that can be used as a raw material of a high-quality and high-performance polycarbonate. According to the present invention, there are provided a high boiling point material separating column A and a diphenyl carbonate purifying column B each comprising a continuous multi-stage distillation column having specified structures, and there is provided a specific process that enables a high-purity diphenyl carbonate which is important as a raw material of a high-quality and high-performance polycarbonate to be produced stably for a prolonged period of time on an industrial scale of not less than 1 ton / hr from a reaction mixture containing the diphenyl carbonate using an apparatus in which these two continuous multi-stage distillation columns are connected together. |
申请公布号 |
EP1783112(A4) |
申请公布日期 |
2008.08.20 |
申请号 |
EP20050780916 |
申请日期 |
2005.08.24 |
申请人 |
ASAHI KASEI CHEMICALS CORPORATION |
发明人 |
FUKUOKA, SHINSUKE;HACHIYA, HIROSHI;MATSUZAKI, KAZUHIKO;MIYAJI, HIRONORI |
分类号 |
C07C68/06;B01D3/16;B01D3/22;C07B61/00;C07C68/08;C07C69/96 |
主分类号 |
C07C68/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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