摘要 |
<p>The present invention concerns a new efficient method for the selective transformation, under mild conditions and in aqueous medium, of gaseous (ethane, propane and n-butane) and liquid (n-pentane, n-hexane, cyclopentane and cyclohexane) alkanes into carboxylic acids bearing one more carbon atom, characterized by a single-pot low- temperature (25-60 °C) reaction of the alkane with carbon monoxide in water/acetonitrile liquid medium, either in the absence or in the presence of a metal catalyst, in systems containing also an oxidant (a peroxodisulphate salt).</p> |
申请人 |
INSTITUTO SUPERIOR TECNICO;POMBEIRO, ARMANDO,;KIRILLOVA, MARINA;KIRILLOV, ALEXANDER;SILVA, JOSE ARMANDO;FRAUSTO DA SILVA, JOAO |
发明人 |
POMBEIRO, ARMANDO,;KIRILLOVA, MARINA;KIRILLOV, ALEXANDER;SILVA, JOSE ARMANDO;FRAUSTO DA SILVA, JOAO |