| 摘要 |
<p>A process of preparing a nanocomposite comprising an elastomer and at least partially exfoliated, intercalated water-swellable clay is disclosed. The method comprises the steps of
(A) forming a first blend of water-swelled clay and anionic polymer particle emulsion by blending:
(1) an aqueous mixture comprising water and a multilayered water-swellable clay, and
(2) an emulsion of anionic synthetic vinylpyridine-styrene-butadiene terpolymer (VPSBR) elastomer particles as an aqueous pre-formed elastomer emulsion; and
(B) blending with said first blend an aqueous mixture comprising water and inorganic acid.
Furthermore, a tire is disclosed comprising a rubber composition comprising:
an vinylpyridine-styrene-butadiene (VPSBR) elastomer derived from monomers comprising vinylpyridine monomers, styrene, and butadiene, wherein the VPSBR comprises from 0.1 to 8 percent by weight of vinylpyridine; and
from 5 to 15 parts by weight, per 100 parts by weight of VPSBR, of an at least partially exfoliated clay.</p> |
