发明名称 FLUOROADAMANTANE DERIVATIVE
摘要 Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials. A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are -CFH- or -CF<SUB>2</SUB>-; R<SUP>F </SUP>is a perfluoroalkyl group or the like; X<SUP>10 </SUP>is F or the like; Y<SUP>2 </SUP>is H or OH; Y<SUP>3 </SUP>is H or R<SUP>F</SUP>COO-; Y<SUP>4 </SUP>is H, F or R<SUP>F</SUP>COO-; Y<SUP>5 </SUP>is H, F, R<SUP>F</SUP>COO- or OH; Y<SUP>0 </SUP>is H, F, -OCOCR<SUP>1</SUP>-CH<SUB>2 </SUB>or OH: R<SUP>1 </SUP>is a hydrogen atom, a methyl group or the like; and X<SUP>11 </SUP>is OH or a halogen atom:
申请公布号 US2008132736(A1) 申请公布日期 2008.06.05
申请号 US20080020863 申请日期 2008.01.28
申请人 ASAHI GLASS COMPANY, LIMITED 发明人 WANG SHU-ZHONG;HOSHINO TAIKI;KASHIWAGI KIMIAKI;OKAZOE TAKASHI;MUROTANI EISUKE;ITO MASAHIRO;WATANABE KUNIO
分类号 C07C35/22;C07C35/48;C07C35/52;C07C67/14;C07C69/00;C07C69/54 主分类号 C07C35/22
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