摘要 |
The invention relates to a method for producing organic chlorides, wherein the chlorine atom is connected to a CH2-group, by reacting the corresponding alcohols with thionyl chloride in the presence of a triaryl phosphinoxide at a temperature of between 20-200 °C and at a pressure of 0.01-10 MPa abs, wherein the triaryl phosphinoxide is used in a molar ratio in relation to the amount of substance of the OH groups of 0.0001 0.5 which is to be chlorinated.
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