发明名称 |
INTEGRATED PROCESS FOR PREPARING TRIOXANE FROM FORMALDEHYDE |
摘要 |
The invention relates to an integrated process for preparing trioxane from formaldehyde, comprising the steps of: a) a stream A 1 comprising water and formaldehyde and a recycle stream B 2 consisting substantially of water and formaldehyde are fed to a trioxane synthesis reactor and allowed to react to obtain a product stream A 2 comprising trioxane, water and formaldehyde; b) stream A 2 is fed to a first low-pressure distillation column and distilled at a pressure of from 0.1 to 2.5 bar to obtain a stream B 1 enriched in trioxane and additionally comprising water and formaldehyde, and the recycle stream B 2 consisting substantially of formaldehyde and water; c) stream B 1 and a recycle stream D 1 comprising trioxane, water and formaldehyde are fed to a second low-pressure distillation column and distilled at a pressure of from 0.1 to 2.5 bar to obtain a stream C 1 comprising predominantly trioxane and additionally formaldehyde and water, and a stream C 2 consisting substantially of formaldehyde and water; d) stream C 1 is fed to a high-pressure distillation column and distilled at a pressure of from 0.2 to 17.5 bar to obtain the recycle stream D 1 and a product stream D 2 consisting substantially of trioxane, in which a removal of the low boilers present in streams B 1 or C 1 may be undertaken between steps b) and c) or c) and d). |
申请公布号 |
EP1912965(A1) |
申请公布日期 |
2008.04.23 |
申请号 |
EP20060764207 |
申请日期 |
2006.07.19 |
申请人 |
BASF SE |
发明人 |
LANG, NEVEN;STROEFER, ECKHARD;STAMMER, ACHIM;FRIESE, THORSTEN;SIEGERT, MARKUS;HASSE, HANS;GRUETZNER, THOMAS;BLAGOV, SERGEJ |
分类号 |
C07D323/06 |
主分类号 |
C07D323/06 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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