发明名称 |
Use of a mixture of two metallocene regioisomers as catalyst component for preparing bimodal isotactic polyolefins |
摘要 |
<p>Use for preparing isotactic polyolefins of a metallocene catalyst component, which has the general formula: R" (CpR1R2) (Cp'Rn') MQ2 wherein Cp is a substituted cyclopentadienyl ring; Cp' is a substituted or unsubstituted fluorenyl ring; R" is a structural bridge imparting stereorigidity to the component; R1 is a substituent on the cyclopentadienyl ring which is distal to the bridge, which distal substituent comprises a bulky group of the formula XR*3 in which X is chosen from Group IVA, and each R* is the same or different and chosen from hydrogen or hydrocarbyl of from 1 to 20 carbon atoms, R2 is a substituent on the cyclopentadienyl ring which is proximal to the bridge and positioned non-vicinal to the distal substituent and is of the formula YR#3 in which Y is chosen from group IVA, and each R# is the same or different and chosen from hydrogen or hydrocarbyl of 1 to 7 carbon atoms, each R'n is the same or different and is hydrocarbyl having 1 to 20 carbon atoms in whrch o≤n≤8; M is a Group IVB transition metal or vanadium; and each Q is hydrocarbyl having 1 to 20 carbon atoms or is a halogen.</p> |
申请公布号 |
EP1283223(B1) |
申请公布日期 |
2008.04.09 |
申请号 |
EP20020078802 |
申请日期 |
1998.05.26 |
申请人 |
TOTAL PETROCHEMICALS RESEARCH FELUY |
发明人 |
RAZAVI, ABBAS;BELLIA, VINCENZO |
分类号 |
C08F4/64;C08F10/00;C08F4/642;C08F4/659;C08F110/06 |
主分类号 |
C08F4/64 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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