摘要 |
<P>PROBLEM TO BE SOLVED: To provide a polymerizable composition which does not contain an organic tin catalyst, does not need the addition of a conventional internal mold release agent, and gives a polythiourethane resin suitably used as an optical transparent resin. <P>SOLUTION: A polymerization catalyst contains both an amine compound represented by general formula (1) (wherein, R<SP>1</SP>, R<SP>2</SP>, R<SP>3</SP>are each independently H or a monovalent or more valent linear aliphatic, branched aliphatic, alicyclic or aromatic organic residue which may contain one or more hydroxyl groups or amino groups, or R<SP>1</SP>, R<SP>2</SP>, R<SP>3</SP>may be each bound to each other to form a ring) and a sulfonic acid represented by general formula (2) [(n) is an integer of 1 or 2; R<SP>4</SP>is a monovalent or more valent linear aliphatic, branched aliphatic, alicyclic or aromatic organic residue which may contain one or more hydroxyl groups or amino groups], does not contain a conventional organic tin compound having been used as a catalyst for polythiourethane resins, does not need the addition of a conventional internal mold release agent, and can give polythiourethane resins suitably used as optical transparent resins. <P>COPYRIGHT: (C)2008,JPO&INPIT |