Allyloxytrifluoropropenes

摘要

A process for the preparation of an allyloxytrifluoropropene derivative of the formula CF₃CH-CR¹(OCH₂CR-CH₂) wherein R¹ is hydrogen, fluoro, or an allyloxy group represented by the formula -OCH₂CR-CH₂ wherein R is hydrogen or methyl including contacting (I) a compound represented by the formula CF₃CH-CR²R³ wherein R² is selected from the group consisting of hydrogen, chloro, and fluoro and wherein R³ is chloro or fluoro; and (ii) an allyl alcohol derivative of the formula HOCH₂CR-CH₂ wherein R is selected from the group consisting of: hydrogen and methyl; wherein the contacting is carried out in the presence of a base and optionally a solvent at a temperature and length of time sufficient to produce the allyloxytrifluoropropene derivative. A process for the preparation of polymers of the allyloxytrifluoropropene derivatives is also provided.