| 摘要 |
The invention relates to the new chemical substances of coordination structure, in particular to the crystalline zinc-cuprum (II) aquaaminoorthopyrophosphate of general formula ZnCu(PO)(PO)mNHnHO, where х=1.77 – 3.0; у=2.0-2.69; z=1.33-2.00; m=4.0-5.0; n=4.7-5.6. A process for preparation of crysrtalline zinc-cuprum (II) aquaaminoorthopyrophosphate, containing simultaneously zinc and cuprum (II) cations and orthophosphate and pyrophosphate anions, which is obtained as a product of given composition in cation and anion components, on the basis of mechanical mixture Zn(PO)4HO and CuPO5HO, taken in ratio ZnО : CuO from 1.5 : 1.0 to 1.0 : 1.5, to which the concentrated water solution of ammonia and acetone is added. |
