| 摘要 |
925,085. Semi-conductor devices. PACIFIC SEMICONDUCTORS Inc. July 21, 1959 [July 21, 1958], No. 25032/59. Class 37. A semi-conductor device having a PN junction is provided with a polysiloxane film which seals it from the atmosphere. As shown, Fig. 4, a PN junction 10 has a gold-plated " Kovar " (Registered Trade Mark) or molybdenum tab alloyed to the P layer and a similar tab 19 alloyed to the N layer. The tab alloyed to the Pa layer may be aluminium doped and that alloyed to the gold layer may be phosphorus doped. A gold coated copper electrode 23 is welded to the upper tab and gold coated metal ribbon which may be welded to a heavier electrode 30 is bonded to the lower. A polysiloxane film 32 greater than 1 micron in thickness is then deposited around and surrounding the crystal. To produce the film the device with its electrodes is immersed in an etch containing hydrofluoric and nitric acid and is then immersed in a quench solution comprising primarily an organic liquid which has in its chemical structure a reactive hydroxyl group; a 95% ethanol solution is preferred. This process forms ester groups which are molecularly bonded with the silicon surface. The ester is then reacted with a mixture of organo silicon compound in which a trifunctional monomer predominates. The reactive group X of such monomers having the formula RSX3 can be the hydroxyl group but trihydroxy compounds rapidly auto-polymerize. A tri-alkoxy compound such as ethyl tri-ethoxy silane is preferred as a starting material which is then hydrolised to the hydroxyl compound just prior to use. The reactive groups may also be mercapto, amino or halide groups. The Specification states the addition of di- and monofunctional organo-silanes offer certain advantages. An embodiment is described in which a transistor is mounted in a polysiloxane film. |
