| 摘要 |
A process for working up by distillation the crude products obtained in the process according to DE-A 196 07 954 and containing 1,6-hexanediol (HDO), 1,5-pentanediol (PDO) or caprolactone (CLO) in order to obtain the corresponding pure products, the working-up by distillation being carried out in each case in a dividing wall column (TK) in which a dividing wall (T) is arranged in the longitudinal direction of the column with formation of an upper common column region ( 1 ), a lower common column region ( 6 ), a feed section ( 2, 4 ) having a rectification section ( 2 ) and stripping section ( 4 ), and a take-off section ( 3, 5 ) having a stripping section ( 3 ) and rectification section ( 5 ), with feeding of the respective crude product HDO, PLO or CLO in the middle region of the feed section ( 2, 4 ) and removal of the high boiler fraction (C) from the bottom of the column, of the low boiler fraction (A) via the top of the column and of the medium boiler fraction (B) from the middle region of the take-off section ( 3, 5 ), or in thermally coupled columns.
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