| 摘要 |
FIELD: chemistry of metalloorganic compounds, chemical technology. ^ SUBSTANCE: invention relates to methods for synthesis of novel organoaluminum compounds. Proposed method is carried out by interaction of 1,9-decadiene with ethylaluminum chloride and magnesium powder in the presence of zirconacene dichloride as a catalyst, in argon atmosphere, in tetrahydrofuran (TGF) medium. The reaction time is 8-12 h. The total yield of the end products is 32-48%. Proposed method provides preparing compound of the formula (1): with high selectivity. Synthesis of this compound is not described in special literature. Synthesized compound can be used a component of catalytic systems in processes of oligo- and polymerization of unsaturated compounds and in fine organic and metalloorganic syntheses. ^ EFFECT: improved method of synthesis. ^ 1 tbl, 10 ex |
