| 摘要 |
The invention relates to complex compound of cooper (II) based on N-aryl- or N-alkylamide benzimidazole-2-carbothioic acid of general formula: , (1) wherein R=H, R1=CH3, X=ClO4; R=H, R1=4-ClC6H4, X=ClO4; R=H, R1=4-CH3OC6H4, X=Cl; R=H, R1=4-CH3C6H4, X=Cl; R=H, R1=4-ClC6H4, X=Cl; R=H, R1=CH3, X=Br; R=H, R1=4-CH3OC6H4, X=Br; R=H, R1=4-CH3C6H4, X=Br; R=H, R1=4-BrC6H4, X=Br; R=H, R1=4-ClC6H4, X=Br; R=H, R1=CH3, X=F; R+R1=(CH2CH2)2O, X=F; R=H, R1=CH3, X=BF4; R=H, R1=C6H5, X=BF4; R=H, R1=4-CH3OC6H4, X=BF4; R=H, R1=4-CH3C6H4, X=BF4; R=H, R1=4-ClC6H4, X=BF4; R=H, R1=CH3, X=CF3COO; R+R1=(CH2CH2)2O, X=CF3COO; R=H, R1=C6H5, X=CF3COO; R=H, R1=4-CH3OC6H4, X=CF3COO; R=H, R1=4-CH3C6H4, X=CF3COO; R=H, R1=4-BrC6H4, X=CF3COO; R=H, R1=4-ClC6H4, X=CF3COO; R=H, R1=CH3, X=ClCH2COO; R+R1=(CH2CH2)2O, X=ClCH2COO; R=H, R1=CH3, X=CCl3COO; R=H, R1=4-CH3OC6H4, X=CCl3COO; R=H, R1=4-ClC6H4, X=CCl3COO; R=H, R1=CH3, X=1/2 SiF6; R=H, R1=4-CH3C6H4, X=1/2 SiF6; R=H, R1=4-CH3OC6H4, X=1/2 SiF6; R=H, R1=4-BrC6H4, X=1/2 SiF6; R=H, R1=4-ClC6H4, X=1/2 SiF6. The invention relates as well to a composition of antifriction coating based on aromatic polyamide, which contains mineral carbon and complex compound of general formula (1).
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