Ruthenium Complex and Process for Producing Tert-Alkyl Alcohol Therewith
摘要
A tert-alkyl ketone, pinacolone was hydrogenated under pressurized hydrogen in the presence of a ruthenium complex (S)-1 and a base, and corresponding (S)-3,3,-dimethyl-2-butanol was thereby obtained in 100% yield and 97% ee.
申请公布号
US2007265448(A1)
申请公布日期
2007.11.15
申请号
US20050665919
申请日期
2005.10.24
申请人
KANTO KAGAKU KABUSHIKI KAISHA;NAGOYA INDUSTRIAL SCIENCE RESEARCH INSITUTE