| 摘要 |
Ethanol is dehydrogenated in the presence of hydrogen over a dehydrogenation catalyst, for example, a copper on silica catalyst. The liquefiable products present in the resulting intermediate reaction product mixture are selectively hydrogenated over a suitable catalyst, such as 5% ruthenium on carbon, so as selectively to hydrogenate reactive carbonyl-containing by-products to the corresponding alcohols. Butan-2-one and n-butyraldehyde, which would otherwise cause difficulties in purification of the ethyl acetate product, due to the proximity of their boiling points to that of ethyl acetate, are thereby hydrogenated to 2-butanol and n-butanol respectively. A two stage distillation procedure is then used to purify the selectively hydrogenated product. The first distillation zone is typically operated at less than about 4 bar (4 .times. 10 5 Pa) absolute, while the second distillation zone is typically operated at a pressure of from about 4 bar (4 .times. 10 5 Pa) absolute to about 25 bar (2.5 .times. 10 6 Pa). A first distillate of ethyl acetate, ethanol and water produced in the first distillation zone is redistilled in the second distillation zone, thereby producing a bottom product comprising, typically, from about 99.8 mol % to about 99.95 mol % ethyl acetate and an overhead second distillate, which has a different composition from that produced in the firs t distillation zone and which is returned to the first distillation zone, preferably at a point above the feed point for the liquefiable product s of the selectively hydrogenated reaction product mixture.
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