发明名称 COMPOUND COMPRISING THE COMBINATION OD A FIRST PHOSPHOMOLYBDENUM CRYSTAL PHASE AND A SECOND CRYSTAL PHASE, AND USE THEREOF AS ALKANE OXIDATION CATALYST
摘要 The invention concerns a compound comprising a combination of two crystal phases. The first crystal phase corresponds to the formula: A<SUB>a</SUB>E<SUB>b</SUB>V<SUB>c</SUB>Mo<SUB>d</SUB>P<SUB>e</SUB>O<SUB>f</SUB>H<SUB>g</SUB> wherein A is an alkali-metal; E is Te, Sb or Bi; and 0 = a = 3, 0 < b = 3, 0 = c = 3, 0 < d = 13, 0 < e = 2, 0 = g = 3. The second crystal phase corresponds to the formula Z<SUB>g</SUB>Mo<SUB>h</SUB>X<SUB>i</SUB>O<SUB>j</SUB> wherein: Z is selected among trivalent rare earths; X is selected among the elements V, Ga, Fe, Bi, Ce, Ti, Sb, Mn, Zn, Te; and 0 < g = 3, 0 = h = 3, 0 = i = 1. The indices f and j represent the number of oxygen atoms required for satisfying the relative valency and atomic proportions of the elements present. The invention also concerns the method for preparing said compound, and its use in particular as catalyst for oxidizing alkanes.
申请公布号 WO2007093702(A3) 申请公布日期 2007.10.04
申请号 WO2007FR00260 申请日期 2007.02.14
申请人 CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S);UNIVERSITE DU MAINE;MILLET, JEAN-MARC;LACORRE, PHILIPPE;HUYNH, QUYEN 发明人 MILLET, JEAN-MARC;LACORRE, PHILIPPE;HUYNH, QUYEN
分类号 B01J27/199;B01J35/02;B01J37/04;C07C45/33;C07C45/35;C07C51/215;C07C51/25 主分类号 B01J27/199
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