发明名称 Process for Producing Meth( Acrylic) Acid or (Meth) Acrolein
摘要 A producing method of (meth)acrolein or (meth)acrylic acid where by use of a multi-tubular reactor that has a plurality of reaction tubes filled with a catalyst, catalytic gas phase oxidation of propylene, propane, isobutylene or (meth)acrolein is carried out in the presence of a composite oxide catalyst by use of molecular oxygen or a gas containing molecular oxygen, in which method (meth)acrolein or (meth)acrylic acid can be obtained stably in high yield for a long period of time without allowing the activity of the catalyst to decrease locally (disproportionately) and extremely. A temperature difference between a temperature of a heat medium at the beginning of operation and a peak temperature of the catalyst is set in a range of 20 to 80° C., and during operations a change of the peak temperature T of the catalyst in a tube axis direction is maintained in a definite range.
申请公布号 US2007208201(A1) 申请公布日期 2007.09.06
申请号 US20040547004 申请日期 2004.10.27
申请人 MITSUBISHI CHEMICAL CORPORATION 发明人 OGAWA YASUSHI;YADA SHUHEI;SUZUKI YOSHIRO;TAKASAKI KENJI;JINNO KIMIKATSU
分类号 C07C51/16;C07B61/00;C07C27/14;C07C45/35;C07C47/22;C07C51/215;C07C51/235;C07C51/25;C07C57/05;C07C57/055 主分类号 C07C51/16
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