摘要 |
<P>PROBLEM TO BE SOLVED: To provide a catalyst for producing ε-caprolactam hard to cause the deterioration of activity in the gaseous phase Beckman rearrangement reaction of cyclohexanone oxime, and a production method of ε-caprolactam using the catalyst. <P>SOLUTION: The catalyst for producing ε-caprolactam is constituted by supporting a catalyst component essentially based on pentasyl type zeolite on a carrier with a geometrical surface area per volume of 4,000 m<SP>2</SP>/m<SP>3</SP>or above. In the production method of ε-caprolactam, cyclohexanone oxime is subjected to gaseous phase Beckmann rearrangement reaction in the presence of a catalyst and the catalyst for producing ε-caprolactam is used as the catalyst. <P>COPYRIGHT: (C)2007,JPO&INPIT |