| 摘要 |
Polycarbonates are made by passing a carbonyl halide through a slurry comprising a suspension of a mixture of a dihydric phenol and at least 2 moles per mole of dihydric phenol, of an inorganic acid acceptor in a single liquid phase comprising an inert organic liquid which is a solvent for the polycarbonate but a nonsolvent for the dihydric phenol and the acid acceptor, and separating the resulting solid phase from the single liquid phase which comprises a solution of the polycarbonate in the organic liquid. The acid acceptor is an alkali or alkaline earth metal hydroxide, carbonate, bicarbonate or phosphate. The organic liquid may be methylene chloride, 1,2-dichloroethane or chlorobenzene. The dihydric phenol may be hydroquinone; resorcinol; 2,2-bis-(3-methyl-4-hydroxyphenyl)propane; p,p1-dihydroxydiphenyl ether; or, most preferably, bisphenol-A. The reaction mixture may also include (a) a dicarboxylic acid, e.g. isophthalic acid, (h) a hydroxyl terminated polyester, e.g. poly-(neopentyl glycol adipate), (c) a glycol, (d) a chain terminator, e.g. phenol, p-tertiary butyl phenol, methanol, ethanol, benzoic acid or acetic acid or (e) a catalyst, e.g. a tertiary amine, a quarternary ammonium compound or a quarternary phosphonium compound. At the end of the reaction the liquid phase may be separated from the solid phase by filtration or centrifugation followed by decantation. The polycarbonate is then recovered from the liquid phase by precipitation with a non-solvent (e.g. an aliphatic hydrocarbon or an alcohol) or by evaporation of the solvent. Uses.-Films, fibres, moulded or extruded parts, surface coatings. |
