<p>Before a crystallization step in which a carboxylic acid is crystallized from a carboxylic-acid-containing liquid in crystallization tanks (12) and (13) each having a cooling surface, a preliminary step is conducted in which at least part of the carboxylic-acid-containing liquid is fed to a cooling device (11) equipped with cooling surfaces (15) and (16) and scraping means (18) and (19) for scraping the cooling surfaces and is cooled from a temperature exceeding the crystallization initiation temperature to a temperature not higher than the crystallization initiation temperature. This process is preferable especially when the carboxylic acid is acrylic acid and/or methacrylic acid.</p>
申请公布号
WO2007088981(A1)
申请公布日期
2007.08.09
申请号
WO2007JP51827
申请日期
2007.02.02
申请人
MITSUBISHI RAYON CO., LTD.;TANAKA, SHIGEHO;ANDO, YOSHIMASA;SUGIYAMA, MIEZI;SATO, HARUKI